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BOR KARBÜR TAKVİYELİ ALÜMİNYUM ESASLI KOMPOZİT MALZEMELERİN TUZLU ORTAMDA KOROZYON DAVRANIŞININ İNCELENMESİ

Yıl 2019, Cilt: 8 Sayı: 2, 1135 - 1142, 31.07.2019

Kubilay Karacif Hasan Karabulut Ramazan Çıtak

https://doi.org/10.28948/ngumuh.598105

Öz

   Bu çalışmada, toz metalurjisi yöntemi
kullanılarak elde edilen bor karbür (B4C) takviyeli alüminyum esaslı
kompozit malzemelerin tuzlu ortamdaki korozyon davranışları incelenmiştir.
Üretim esnasında, alüminyum ve bor karbür tozlarının homojen şekilde birbiri
içerisinde dağılımını sağlamak için bir saat karıştırma veya farklı sürelerde
mekanik alaşımlama işlemleri uygulanmıştır.  Karıştırma veya farklı sürelerde uygulanan mekanik
alaşımlama işlemleri sonrasında presleme ve sinterleme yapılarak elde edilen bor
karbür takviyeli alüminyum esaslı kompozit malzemelere %3,5’luk tuzlu su (NaCl)
ortamında potansiyodinamik korozyon testleri uygulanmıştır. Elektrokimyasal
korozyon testleri sonucunda mekanik alaşımlama süresinin artması ile malzemenin
korozyon hızının arttığı, korozyon dayanımının azaldığı belirlenmiştir.



 

Anahtar Kelimeler

Alüminyum bor karbür toz metalurjisi mekanik alaşımlama korozyon

Teşekkür

Proje desteği için Gazi Üniversitesi BAP Birimine teşekkür ederiz.

Kaynakça

  • [1] RIAHI, A.R., ALPAS, A.T., “The role of tribo-layers on the sliding wear behavior of graphitic aluminum matrix composites”, Wear, 251, 1396-1407, 2001.
  • [2] JUN D., LIU, Y.H., YU, S.R., LI, W.F., “Dry sliding friction and wear properties of Al2O3 and carbon short fibres reinforced Al-12Si alloy hybrid composites”, Wear, 257, 930-940, 2004.
  • [3] PARDO, A., MERINO, M.C., MERINO, S., VIEJO, F., CARBONERAS, M., ARRABAL, R., “Influence of reinforcement proportion and matrix composition on pitting corrosion behavior of cast aluminum matrix composites (A3xx.x/SiCp)”, Corrosion Science, 47, 1750-1764, 2005.
  • [4] DE SALAZAR, J.M.G., URENA, A., MANZANEDO, S., BARRENA, M.I., “Corrosion behavior of AA5950 and AA6994 reinforced with Al2O3 particles in aerated %3.5 chloride solutions: potentiodynamic measurements and microstructure evaluation”, Corrosion Science, 41, 529-545, 1999.
  • [5] HU, J., CHU, W.Y., FEI, W.D., ZHAO, L.C., “Effect of interfacial reaction on corrosion behavior of alumina borate whisker reinforced 6061 Al composite”, Materials Science and Engineering A, 374, 153-159, 2004.
  • [6] SARASWATHI, Y.L., DAS, S., MONDAL, D.P., “Influence of microstructure and experimental parameters on the erosion-corrosion behavior of Al alloy composites”, Materials Science and Engineering A, 425, 244-254, 2006.
  • [7] DOBRZANSKI, L.A., WLODARCZYK, A., ADAMIAK, M., “Structure, properties and corrosion resistance of PM composite materials based on EN AW-2124 aluminum alloy reinforced With The Al2O3 Ceramic Particles”, Journal of Materials Processing Technology, 162, 27-32, 2005.
  • [8] QIAO, Y., QU, L., ZHANG, X., ZHANG, H., “Boron carbide composite ceramic preparation and corrosion behavior in simulated seawater”, Ceramics International, 41, 5026-5031, 2015.
  • [9] KATKAR, V.A., GUNASEKARAN, G., RAO, A.G., KOLI, P.M., “Effect of the reinforced boron carbide particulate content of AA6061 alloy on formation of the passive film in seawater”, Corrosion Science, 53, 2700-2712, 2011.
  • [10] HAN, Y.M., GALLANT, D., CHEN, X.G., “Galvanic corrosion associated with Al–B4C composites/SS304 and Al–B4C composites/AA6061 couples in NaCl and H3BO3 solutions”, Electrochimica Acta, 94, 134-142, 2013.
  • [11] SURYANARAYANA, C., “Mechanical Alloying And Milling”, Progress in Materials Science, 46, 1-184, 2001.
  • [12] TOPTAN, F., ALVES, A.C., KERTI, I., ARIZA, E., ROCHA, L.A., “Corrosion and tribocorrosion behaviour of Al–Si–Cu–Mg alloy and its composites reinforced with B4C particles in 0.05M NaCl solution”, Wear, 306, 27-35, 2013.
  • [13] HAN, Y.M., GALLANT, D., CHEN, X.G., “Corrosion inhibition of Al-B4C metal matrix composites in a NaCl solution by benzotriazole”, Materials Chemistry and Physics, 139, 187-195, 2013.
  • [14] FRANKEL, G.S., “Pitting corrosion of metals; a summary of the critical factors”, Journal of Electrochemical Society, 145, 2186-2198, 1998.
  • [15] XUE, W., WU, X., LI, W., TIAN, H., “Anti-corrosion film on 2024/SiC aluminum matrix composite fabricated by microarc oxidation in silicate electrolyte”, Journal of Alloys Compounds, 425, 302-306, 2006.
  • [16] MONTOYA-DÁVILA, M., PECH-CANUL, M.I., PECH-CANUL, M.A., “Effect of SiCp multimodal distribution on pitting behavior of Al/SiCp composites prepared by reactive infiltration”, Powder Technology, 195, 196-202, 2009.
  • [17] FENG, Z., LIN, C., “Pitting behavior of SiCp/2024 Al metal matrix composites”, Journal of Materials Science, 33, 5637-5642, 1998.
  • [18] ZHANG, Z., CHEN, X.G., CHARETTE, A., “Fluidity and microstructure of an Al–10% B4C composite”, Journal of Materials Science, 44, 492-501, 2009.
  • [19] ZHANG, Z., FORTIN, K., CHARETTE, A., CHEN, X.G., “Effect of titanium on microstructure and fuidity of Al–B4C composites”, Journal of Materials Science, 46, 3176-3185, 2011.
  • [20] HAN, Y., GALLANT, D., CHEN, X.G., “Investigation on corrosion behavior of the Al–B4C metal matrix composite in a mildly oxidizing aqueous environment”, Corrosion, 67, 115005-11, 2011.
  • [21] SHOROWORDI, K.M., LAOUI, T., HASEEB, A.S.M.A., CELIS, J.P., FROYEN, L., "Microstructure and interface characteristics of B4C, SiC and Al2O3 reinforced Al matrix composites: a comparative study", Journal of Materials Processing Technology 142, 738–743, 2003.
  • [22] KERTİ, I., TOPTAN, F., "Microstructural variations in cast B4C-reinforced aluminium matrix composites (AMCs)", Materials Letters 62, 1215–1218, 2008.
  • [23] BARADESWARAN, A., PERUMAL, A. E., "Influence of B4C on the tribological and mechanical properties of Al 7075–B4C composites", Composites: Part B 54, 146–152, 2013.
  • [24] KARABULUT, H., ÇITAK, R., ÇİNİCİ, H., "Mekanik Alaşımlama Süresinin Al + % 10 Al2O3 Kompozitlerde Eğme Dayanımına Etkisi", Gazi Üniv. Müh. Mim. Fak. Der., 28: 3, 635-643, 2013.
  • [25] LEE, W., KWUN, S. I., “The effects of process control agents on mechanical alloying mechanisms in the Ti---Al system”, Journal of Alloys and Compounds, 240: 193-199, 1996.
  • [26] ARIK, H., TÜRKER, M., “Production and characterization of in situ Fe-Fe3C composite produced by mechanical alloying”, Materials & Design, 28: 140-146, 2005.
  • [27] SARITAŞ, S., TÜRKER, M. DURLU, N., "Toz Metalurjisi ve Parçacıklı Malzeme İşlemleri", Türk Toz Metalurjisi Derneği Yayınları:05, Ankara, 2007.

THE INVESTIGATION OF CORROSION BEHAVIOR OF ALUMINUM COMPOSITES REINFORCED WITH BORON CARBIDE IN SALTWATER MEDIUM

Yıl 2019, Cilt: 8 Sayı: 2, 1135 - 1142, 31.07.2019

Kubilay Karacif Hasan Karabulut Ramazan Çıtak

https://doi.org/10.28948/ngumuh.598105

Öz

   In the study, corrosion behaviors of powder
metal aluminum composites reinforced with boron carbide (B4C) were
investigated in saltwater medium. For the production of composite specimens, one
hour mixing or mechanical alloying for different durations was applied to
ensure uniform distribution of aluminum and boron carbide powders. After
pressing and sintering treatment of specimens, electrochemical corrosion tests
were applied in 3.5% NaCl solution by potentiodynamic methods. According to electrochemical
corrosion test results, it was determined that the corrosion rate of material was
increased and corrosion resistance decreased with the increase of mechanical
alloying duration.

Anahtar Kelimeler

Aluminum boron carbide powder metallurgy mechanical alloying corrosion

Kaynakça

  • [1] RIAHI, A.R., ALPAS, A.T., “The role of tribo-layers on the sliding wear behavior of graphitic aluminum matrix composites”, Wear, 251, 1396-1407, 2001.
  • [2] JUN D., LIU, Y.H., YU, S.R., LI, W.F., “Dry sliding friction and wear properties of Al2O3 and carbon short fibres reinforced Al-12Si alloy hybrid composites”, Wear, 257, 930-940, 2004.
  • [3] PARDO, A., MERINO, M.C., MERINO, S., VIEJO, F., CARBONERAS, M., ARRABAL, R., “Influence of reinforcement proportion and matrix composition on pitting corrosion behavior of cast aluminum matrix composites (A3xx.x/SiCp)”, Corrosion Science, 47, 1750-1764, 2005.
  • [4] DE SALAZAR, J.M.G., URENA, A., MANZANEDO, S., BARRENA, M.I., “Corrosion behavior of AA5950 and AA6994 reinforced with Al2O3 particles in aerated %3.5 chloride solutions: potentiodynamic measurements and microstructure evaluation”, Corrosion Science, 41, 529-545, 1999.
  • [5] HU, J., CHU, W.Y., FEI, W.D., ZHAO, L.C., “Effect of interfacial reaction on corrosion behavior of alumina borate whisker reinforced 6061 Al composite”, Materials Science and Engineering A, 374, 153-159, 2004.
  • [6] SARASWATHI, Y.L., DAS, S., MONDAL, D.P., “Influence of microstructure and experimental parameters on the erosion-corrosion behavior of Al alloy composites”, Materials Science and Engineering A, 425, 244-254, 2006.
  • [7] DOBRZANSKI, L.A., WLODARCZYK, A., ADAMIAK, M., “Structure, properties and corrosion resistance of PM composite materials based on EN AW-2124 aluminum alloy reinforced With The Al2O3 Ceramic Particles”, Journal of Materials Processing Technology, 162, 27-32, 2005.
  • [8] QIAO, Y., QU, L., ZHANG, X., ZHANG, H., “Boron carbide composite ceramic preparation and corrosion behavior in simulated seawater”, Ceramics International, 41, 5026-5031, 2015.
  • [9] KATKAR, V.A., GUNASEKARAN, G., RAO, A.G., KOLI, P.M., “Effect of the reinforced boron carbide particulate content of AA6061 alloy on formation of the passive film in seawater”, Corrosion Science, 53, 2700-2712, 2011.
  • [10] HAN, Y.M., GALLANT, D., CHEN, X.G., “Galvanic corrosion associated with Al–B4C composites/SS304 and Al–B4C composites/AA6061 couples in NaCl and H3BO3 solutions”, Electrochimica Acta, 94, 134-142, 2013.
  • [11] SURYANARAYANA, C., “Mechanical Alloying And Milling”, Progress in Materials Science, 46, 1-184, 2001.
  • [12] TOPTAN, F., ALVES, A.C., KERTI, I., ARIZA, E., ROCHA, L.A., “Corrosion and tribocorrosion behaviour of Al–Si–Cu–Mg alloy and its composites reinforced with B4C particles in 0.05M NaCl solution”, Wear, 306, 27-35, 2013.
  • [13] HAN, Y.M., GALLANT, D., CHEN, X.G., “Corrosion inhibition of Al-B4C metal matrix composites in a NaCl solution by benzotriazole”, Materials Chemistry and Physics, 139, 187-195, 2013.
  • [14] FRANKEL, G.S., “Pitting corrosion of metals; a summary of the critical factors”, Journal of Electrochemical Society, 145, 2186-2198, 1998.
  • [15] XUE, W., WU, X., LI, W., TIAN, H., “Anti-corrosion film on 2024/SiC aluminum matrix composite fabricated by microarc oxidation in silicate electrolyte”, Journal of Alloys Compounds, 425, 302-306, 2006.
  • [16] MONTOYA-DÁVILA, M., PECH-CANUL, M.I., PECH-CANUL, M.A., “Effect of SiCp multimodal distribution on pitting behavior of Al/SiCp composites prepared by reactive infiltration”, Powder Technology, 195, 196-202, 2009.
  • [17] FENG, Z., LIN, C., “Pitting behavior of SiCp/2024 Al metal matrix composites”, Journal of Materials Science, 33, 5637-5642, 1998.
  • [18] ZHANG, Z., CHEN, X.G., CHARETTE, A., “Fluidity and microstructure of an Al–10% B4C composite”, Journal of Materials Science, 44, 492-501, 2009.
  • [19] ZHANG, Z., FORTIN, K., CHARETTE, A., CHEN, X.G., “Effect of titanium on microstructure and fuidity of Al–B4C composites”, Journal of Materials Science, 46, 3176-3185, 2011.
  • [20] HAN, Y., GALLANT, D., CHEN, X.G., “Investigation on corrosion behavior of the Al–B4C metal matrix composite in a mildly oxidizing aqueous environment”, Corrosion, 67, 115005-11, 2011.
  • [21] SHOROWORDI, K.M., LAOUI, T., HASEEB, A.S.M.A., CELIS, J.P., FROYEN, L., "Microstructure and interface characteristics of B4C, SiC and Al2O3 reinforced Al matrix composites: a comparative study", Journal of Materials Processing Technology 142, 738–743, 2003.
  • [22] KERTİ, I., TOPTAN, F., "Microstructural variations in cast B4C-reinforced aluminium matrix composites (AMCs)", Materials Letters 62, 1215–1218, 2008.
  • [23] BARADESWARAN, A., PERUMAL, A. E., "Influence of B4C on the tribological and mechanical properties of Al 7075–B4C composites", Composites: Part B 54, 146–152, 2013.
  • [24] KARABULUT, H., ÇITAK, R., ÇİNİCİ, H., "Mekanik Alaşımlama Süresinin Al + % 10 Al2O3 Kompozitlerde Eğme Dayanımına Etkisi", Gazi Üniv. Müh. Mim. Fak. Der., 28: 3, 635-643, 2013.
  • [25] LEE, W., KWUN, S. I., “The effects of process control agents on mechanical alloying mechanisms in the Ti---Al system”, Journal of Alloys and Compounds, 240: 193-199, 1996.
  • [26] ARIK, H., TÜRKER, M., “Production and characterization of in situ Fe-Fe3C composite produced by mechanical alloying”, Materials & Design, 28: 140-146, 2005.
  • [27] SARITAŞ, S., TÜRKER, M. DURLU, N., "Toz Metalurjisi ve Parçacıklı Malzeme İşlemleri", Türk Toz Metalurjisi Derneği Yayınları:05, Ankara, 2007.
Toplam 27 adet kaynakça vardır.

Ayrıntılar

Birincil Dil Türkçe
Konular Malzeme Üretim Teknolojileri
Bölüm Malzeme ve Metalürji Mühendisliği
Yazarlar

Kubilay Karacif 0000-0001-7180-7897

Hasan Karabulut Bu kişi benim 0000-0002-3370-9994

Ramazan Çıtak Bu kişi benim 0000-0001-7899-8091

Yayımlanma Tarihi 31 Temmuz 2019
Gönderilme Tarihi 23 Kasım 2018
Kabul Tarihi 6 Nisan 2019
Yayımlandığı Sayı Yıl 2019 Cilt: 8 Sayı: 2

Kaynak Göster

APA Karacif, K., Karabulut, H., & Çıtak, R. (2019). BOR KARBÜR TAKVİYELİ ALÜMİNYUM ESASLI KOMPOZİT MALZEMELERİN TUZLU ORTAMDA KOROZYON DAVRANIŞININ İNCELENMESİ. Niğde Ömer Halisdemir Üniversitesi Mühendislik Bilimleri Dergisi, 8(2), 1135-1142. https://doi.org/10.28948/ngumuh.598105
AMA Karacif K, Karabulut H, Çıtak R. BOR KARBÜR TAKVİYELİ ALÜMİNYUM ESASLI KOMPOZİT MALZEMELERİN TUZLU ORTAMDA KOROZYON DAVRANIŞININ İNCELENMESİ. NÖHÜ Müh. Bilim. Derg. Temmuz 2019;8(2):1135-1142. doi:10.28948/ngumuh.598105
Chicago Karacif, Kubilay, Hasan Karabulut, ve Ramazan Çıtak. “BOR KARBÜR TAKVİYELİ ALÜMİNYUM ESASLI KOMPOZİT MALZEMELERİN TUZLU ORTAMDA KOROZYON DAVRANIŞININ İNCELENMESİ”. Niğde Ömer Halisdemir Üniversitesi Mühendislik Bilimleri Dergisi 8, sy. 2 (Temmuz 2019): 1135-42. https://doi.org/10.28948/ngumuh.598105.
EndNote Karacif K, Karabulut H, Çıtak R (01 Temmuz 2019) BOR KARBÜR TAKVİYELİ ALÜMİNYUM ESASLI KOMPOZİT MALZEMELERİN TUZLU ORTAMDA KOROZYON DAVRANIŞININ İNCELENMESİ. Niğde Ömer Halisdemir Üniversitesi Mühendislik Bilimleri Dergisi 8 2 1135–1142.
IEEE K. Karacif, H. Karabulut, ve R. Çıtak, “BOR KARBÜR TAKVİYELİ ALÜMİNYUM ESASLI KOMPOZİT MALZEMELERİN TUZLU ORTAMDA KOROZYON DAVRANIŞININ İNCELENMESİ”, NÖHÜ Müh. Bilim. Derg., c. 8, sy. 2, ss. 1135–1142, 2019, doi: 10.28948/ngumuh.598105.
ISNAD Karacif, Kubilay vd. “BOR KARBÜR TAKVİYELİ ALÜMİNYUM ESASLI KOMPOZİT MALZEMELERİN TUZLU ORTAMDA KOROZYON DAVRANIŞININ İNCELENMESİ”. Niğde Ömer Halisdemir Üniversitesi Mühendislik Bilimleri Dergisi 8/2 (Temmuz 2019), 1135-1142. https://doi.org/10.28948/ngumuh.598105.
JAMA Karacif K, Karabulut H, Çıtak R. BOR KARBÜR TAKVİYELİ ALÜMİNYUM ESASLI KOMPOZİT MALZEMELERİN TUZLU ORTAMDA KOROZYON DAVRANIŞININ İNCELENMESİ. NÖHÜ Müh. Bilim. Derg. 2019;8:1135–1142.
MLA Karacif, Kubilay vd. “BOR KARBÜR TAKVİYELİ ALÜMİNYUM ESASLI KOMPOZİT MALZEMELERİN TUZLU ORTAMDA KOROZYON DAVRANIŞININ İNCELENMESİ”. Niğde Ömer Halisdemir Üniversitesi Mühendislik Bilimleri Dergisi, c. 8, sy. 2, 2019, ss. 1135-42, doi:10.28948/ngumuh.598105.
Vancouver Karacif K, Karabulut H, Çıtak R. BOR KARBÜR TAKVİYELİ ALÜMİNYUM ESASLI KOMPOZİT MALZEMELERİN TUZLU ORTAMDA KOROZYON DAVRANIŞININ İNCELENMESİ. NÖHÜ Müh. Bilim. Derg. 2019;8(2):1135-42.
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