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Synthesis and characterization of new phosphor based MTiO3

Yıl 2015, Cilt: 2 Sayı: 2, 31 - 47, 20.06.2015

N. Kayacı Serkan Dayan , A. K. Küçük Nilgün Kalaycıoğlu Özpozan , E. Öztürk E. Karacaoğlu

https://doi.org/10.1501/nuclear_0000000011

Öz

In this study, new titanate phosphors were synthesized. The Dy3+, Eu3+, Ho3+ rare-earth ions were used as dopants to CaTiO3, SrTiO3, and BaTiO3 host crystals. The optimization of reaction conditions were carried out by thermogravimetry (TG) and differential thermal analysis (DTA) methods. The mixtures to achieve a solid state reaction were heated in porcelain crucibles for preheating process at 600 oC and 800 oC and final heating process at 1000 oC for 16 hours in the open atmosphere. The reaction products were characterized by X-ray powder diffractions (XRD). Surface investigations and elemental analysis were determined by using SEM-EDX instrument.
Photoluminescence spectrophotometer (PL) was used for the observation of the excitation and emission spectra.

Anahtar Kelimeler

Perovskite Luminescence Phosphors Solid state synthesis techniques XRD

Kaynakça

  • [1] W.J. Jaffe, R. Cook, H. Jaffe, “Piezoelectric ceramics”, Academic Press, New York (1971).
  • [2] M.E. Lines, A.M. Glass, “Principles and applications of ferroelectrics and related materials”, Oxford University Press, Oxford (2001).
  • [3] J.F. Scott, “Applications of modern ferroelectrics”, Science, 315 954–63 (2007).
  • [4] Y. Yang, X.H. Wang, C.K. Sun, L.T. Li, “Photoluminescence of high aspect-ratio PbTiO3 nanotube arrays”, J. Am. Ceram. Soc., 91 3820–2 (2008).
  • [5] G. Nenartaviciene, K. Tonsuaadu, D. Jasaitis, A. Beganskiene, A.Kareiva, “Preparation and characterization of superconducting YBa2(Cu1-xCrx)4O8 oxides by thermal analysis”, J. Therm. Anal. Calorim., 90 173–81 (2007).
  • [6] M. Roy, P. Dave, S.K. Barbar, S. Jangid, D.M. Phase, AM. Awasth, “X-ray, SEM, and DSC studies of ferroelectric Pb1-xBaxTiO3 ceramics”, J. Therm. Anal. Calorim., 101 833–40 (2010).
  • [7] A. Caneiro, L. Mogni, N. Grunbaum, F. Prado, “Physicochemical properties of non-stoichiometric oxides mixed conductors: part I”, J. Therm. Anal. Calorim., 103 597–606 (2011).
  • [8] M.L. Moreira, M.F.C. Gurgel, G.P. Mambrini, E.R. Leite, P.S. Pizani, J.A. Varela, E. Longo “Photoluminescence of barium titanate and barium zirconate in multilayer disordered thin films at room temperature”, J. Phys. Chem. A, 112 8938-8942 (2008).
  • [9] K.M. Lina, C.C. Lina, C.Y. Hsiaob, Y.Y. Lia, “Synthesis of Gd2Ti2O7:Eu3+, V4+ phosphors by sol–gel process and its luminescent properties”, J. Lumin, 127 561-567 (2007).
  • [10] G.F.G. Freitas, R.S. Nasar, M. Cerqueira, D.M.A. Melo, E. Longo, J.A. Varel, “Luminescence in semi-crystalline zirconium titanate doped with lanthanum”, Mater. Sci. Eng. A., 434 19-22 (2006).
  • [11] I. Wuled Lenggoro, C. Panatarani, K. Okuyama, “One-step synthesis and photoluminescence of doped strontium titanate particles with controlled morphology”, Mater. Sci.Eng. B. 113 60-66 (2004).
  • [12] J.K. Park, H. Ryu, H.D. Park, S.Y. Choi, “Synthesis of SrTiO3:Al, Pr phosphors from a complex precursor polymer and their luminescent properties”, J Eur Ceram Soc., 21 535-543 (2001).
  • [13] L. Hu, H. Song, G. Pan, B. Yan, R. Qin, Q.Dai, “Enhancement of red spectral emission intensity of Y3Al5O12:Ce3+ phosphor via Pr co-doping and Tb substitution for the application to white LEDs”, J. Lumin. 127 371-376 (2007).
  • [14] A. Sinha, S.R. Nair, P.K. Sinha, “Single step synthesis of Li2TiO3 powder”, J. Nucl. Mater. 399 162-167 (2010).
  • [15] A.T. De Figueiredo, V.M. Longo, S. De Lazaro, V.R. Mastelaro, F.S. De Vicente, A.C. Hernandes, M. Li Siu, J.A. Varela, E. Longo, Blue-green and red photoluminescence in CaTiO3:Sm, Journal of Luminescence. 126, 403–407, (2007).
  • [16] Katsumata, T., Kohno, Y., Kubo, H., Komuro S., Morikawa T., ”Low temperature fluorescence thermometer application of long afterglow phosphorescent SrAl12O19: Eu2+,Dy3+ crystals”, Revıew Of Scientific Instruments, 76, 8, (2005).

Yıl 2015, Cilt: 2 Sayı: 2, 31 - 47, 20.06.2015

N. Kayacı Serkan Dayan , A. K. Küçük Nilgün Kalaycıoğlu Özpozan , E. Öztürk E. Karacaoğlu

https://doi.org/10.1501/nuclear_0000000011

Öz

Kaynakça

  • [1] W.J. Jaffe, R. Cook, H. Jaffe, “Piezoelectric ceramics”, Academic Press, New York (1971).
  • [2] M.E. Lines, A.M. Glass, “Principles and applications of ferroelectrics and related materials”, Oxford University Press, Oxford (2001).
  • [3] J.F. Scott, “Applications of modern ferroelectrics”, Science, 315 954–63 (2007).
  • [4] Y. Yang, X.H. Wang, C.K. Sun, L.T. Li, “Photoluminescence of high aspect-ratio PbTiO3 nanotube arrays”, J. Am. Ceram. Soc., 91 3820–2 (2008).
  • [5] G. Nenartaviciene, K. Tonsuaadu, D. Jasaitis, A. Beganskiene, A.Kareiva, “Preparation and characterization of superconducting YBa2(Cu1-xCrx)4O8 oxides by thermal analysis”, J. Therm. Anal. Calorim., 90 173–81 (2007).
  • [6] M. Roy, P. Dave, S.K. Barbar, S. Jangid, D.M. Phase, AM. Awasth, “X-ray, SEM, and DSC studies of ferroelectric Pb1-xBaxTiO3 ceramics”, J. Therm. Anal. Calorim., 101 833–40 (2010).
  • [7] A. Caneiro, L. Mogni, N. Grunbaum, F. Prado, “Physicochemical properties of non-stoichiometric oxides mixed conductors: part I”, J. Therm. Anal. Calorim., 103 597–606 (2011).
  • [8] M.L. Moreira, M.F.C. Gurgel, G.P. Mambrini, E.R. Leite, P.S. Pizani, J.A. Varela, E. Longo “Photoluminescence of barium titanate and barium zirconate in multilayer disordered thin films at room temperature”, J. Phys. Chem. A, 112 8938-8942 (2008).
  • [9] K.M. Lina, C.C. Lina, C.Y. Hsiaob, Y.Y. Lia, “Synthesis of Gd2Ti2O7:Eu3+, V4+ phosphors by sol–gel process and its luminescent properties”, J. Lumin, 127 561-567 (2007).
  • [10] G.F.G. Freitas, R.S. Nasar, M. Cerqueira, D.M.A. Melo, E. Longo, J.A. Varel, “Luminescence in semi-crystalline zirconium titanate doped with lanthanum”, Mater. Sci. Eng. A., 434 19-22 (2006).
  • [11] I. Wuled Lenggoro, C. Panatarani, K. Okuyama, “One-step synthesis and photoluminescence of doped strontium titanate particles with controlled morphology”, Mater. Sci.Eng. B. 113 60-66 (2004).
  • [12] J.K. Park, H. Ryu, H.D. Park, S.Y. Choi, “Synthesis of SrTiO3:Al, Pr phosphors from a complex precursor polymer and their luminescent properties”, J Eur Ceram Soc., 21 535-543 (2001).
  • [13] L. Hu, H. Song, G. Pan, B. Yan, R. Qin, Q.Dai, “Enhancement of red spectral emission intensity of Y3Al5O12:Ce3+ phosphor via Pr co-doping and Tb substitution for the application to white LEDs”, J. Lumin. 127 371-376 (2007).
  • [14] A. Sinha, S.R. Nair, P.K. Sinha, “Single step synthesis of Li2TiO3 powder”, J. Nucl. Mater. 399 162-167 (2010).
  • [15] A.T. De Figueiredo, V.M. Longo, S. De Lazaro, V.R. Mastelaro, F.S. De Vicente, A.C. Hernandes, M. Li Siu, J.A. Varela, E. Longo, Blue-green and red photoluminescence in CaTiO3:Sm, Journal of Luminescence. 126, 403–407, (2007).
  • [16] Katsumata, T., Kohno, Y., Kubo, H., Komuro S., Morikawa T., ”Low temperature fluorescence thermometer application of long afterglow phosphorescent SrAl12O19: Eu2+,Dy3+ crystals”, Revıew Of Scientific Instruments, 76, 8, (2005).
Toplam 16 adet kaynakça vardır.

Ayrıntılar

Birincil Dil İngilizce
Konular Mühendislik
Bölüm Articles
Yazarlar

N. Kayacı

Serkan Dayan

A. K. Küçük

Nilgün Kalaycıoğlu Özpozan

E. Öztürk

E. Karacaoğlu

Yayımlanma Tarihi 20 Haziran 2015
Gönderilme Tarihi 13 Kasım 2014
Yayımlandığı Sayı Yıl 2015Cilt: 2 Sayı: 2

Kaynak Göster

APA Kayacı, N., Dayan, S., Küçük, A. K., Kalaycıoğlu Özpozan, N., vd. (2015). Synthesis and characterization of new phosphor based MTiO3. Journal of Nuclear Sciences, 2(2), 31-47. https://doi.org/10.1501/nuclear_0000000011
AMA Kayacı N, Dayan S, Küçük AK, Kalaycıoğlu Özpozan N, Öztürk E, Karacaoğlu E. Synthesis and characterization of new phosphor based MTiO3. Journal of Nuclear Sciences. Haziran 2015;2(2):31-47. doi:10.1501/nuclear_0000000011
Chicago Kayacı, N., Serkan Dayan, A. K. Küçük, Nilgün Kalaycıoğlu Özpozan, E. Öztürk, ve E. Karacaoğlu. “Synthesis and Characterization of New Phosphor Based MTiO3”. Journal of Nuclear Sciences 2, sy. 2 (Haziran 2015): 31-47. https://doi.org/10.1501/nuclear_0000000011.
EndNote Kayacı N, Dayan S, Küçük AK, Kalaycıoğlu Özpozan N, Öztürk E, Karacaoğlu E (01 Haziran 2015) Synthesis and characterization of new phosphor based MTiO3. Journal of Nuclear Sciences 2 2 31–47.
IEEE N. Kayacı, S. Dayan, A. K. Küçük, N. Kalaycıoğlu Özpozan, E. Öztürk, ve E. Karacaoğlu, “Synthesis and characterization of new phosphor based MTiO3”, Journal of Nuclear Sciences, c. 2, sy. 2, ss. 31–47, 2015, doi: 10.1501/nuclear_0000000011.
ISNAD Kayacı, N. vd. “Synthesis and Characterization of New Phosphor Based MTiO3”. Journal of Nuclear Sciences 2/2 (Haziran 2015), 31-47. https://doi.org/10.1501/nuclear_0000000011.
JAMA Kayacı N, Dayan S, Küçük AK, Kalaycıoğlu Özpozan N, Öztürk E, Karacaoğlu E. Synthesis and characterization of new phosphor based MTiO3. Journal of Nuclear Sciences. 2015;2:31–47.
MLA Kayacı, N. vd. “Synthesis and Characterization of New Phosphor Based MTiO3”. Journal of Nuclear Sciences, c. 2, sy. 2, 2015, ss. 31-47, doi:10.1501/nuclear_0000000011.
Vancouver Kayacı N, Dayan S, Küçük AK, Kalaycıoğlu Özpozan N, Öztürk E, Karacaoğlu E. Synthesis and characterization of new phosphor based MTiO3. Journal of Nuclear Sciences. 2015;2(2):31-47.