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EFFECT OF CU COATING ON THE PHYSICAL AND ELECTROCHEMICAL PROPERTIES OF CONDUCTIVE PLA FILAMENT

Yıl 2019, Cilt: 3 Sayı: 2, 128 - 136, 31.08.2019

Öz

3D printing, also known as additive manufacturing
(AM), is a new technology that allows to design and production of objects or
functional devices in a single process. 3D technology has expanded its ability
to utilize as scientific research and medical application, recently. As this
technology becomes more widespread, 3D printing systems become more affordable.
Especially, the 3D printing method has been used to perform electrodes
production for electrochemical applications in the last five years. Commonly
known 3D printing filaments are polylactic acid (PLA) or acrylonitrile
butadiene styrene (ABS). Thanks to these conductive materials, it is possible
to modify their material properties to enhance conductivity or other
specifications. In this study, investigation of the electrochemical performance
of the conductive PLA is conducted by electroplating of Cu on the surface.
In
the constant voltage value, current density value of Cu coated electrode is
increased three times. Moreover, the usability of conductive PLA as an
electrical circuit element or electrochemical energy conversion electrode is investigated.
According to the obtained results, in LSV measurements, uncoated PLA and Cu coated
PLA has a maximum current of 0.9A and 2.8A at a constant voltage, respectively.
In the CV measurement, kinetic performance and electrical conductivity properties
are improved in Cu coated PLA sample. In CV measurements,
for different scan rate between 50 mV to 200mV is observed that the current
value of Cu coated PLA is increased for all measurements. In Cu coated PLA, significant
improvement in conductivity is obtained in Electrochemical Impedance
Spectroscopy Analysis (EIS).

Teşekkür

The authors are very grateful to the RİİZ MAKİNE R&D Project Consultancy and Construction Co. Ltd. for their technical support.

Kaynakça

  • [1] Ambrosi A, Moo JGS, Pumera M. Helical 3D‐Printed Metal Electrodes as Custom‐Shaped 3D Platform for Electrochemical Devices. Advanced Functional Materials. 2016;26:698-703.
  • [2] Cheng TS, Nasir MZM, Ambrosi A, Pumera M. 3D-printed metal electrodes for electrochemical detection of phenols. Applied Materials Today. 2017;9:212-9.
  • [3] Browne MP, Novotný F, Sofer Zk, Pumera M. 3D Printed Graphene Electrodes’ Electrochemical Activation. ACS applied materials & interfaces. 2018.
  • [4] Kaya MF, Demir N, Albawabiji MS, Taş M. Investigation of alkaline water electrolysis performance for different cost effective electrodes under magnetic field. International Journal of Hydrogen Energy. 2017;42:17583-92.
  • [5] Huang Y, Kormakov S, He X, Gao X, Zheng X, Liu Y, et al. Conductive Polymer Composites from Renewable Resources: An Overview of Preparation, Properties, and Applications. Polymers. 2019;11:187.
  • [6] Yang S, Castilleja JR, Barrera E, Lozano K. Thermal analysis of an acrylonitrile–butadiene–styrene/SWNT composite. Polymer Degradation and Stability. 2004;83:383-8.
  • [7] Yousefi M, Gholamian F, Ghanbari D, Salavati-Niasari M. Polymeric nanocomposite materials: preparation and characterization of star-shaped PbS nanocrystals and their influence on the thermal stability of acrylonitrile–butadiene–styrene (ABS) copolymer. Polyhedron. 2011;30:1055-60.
  • [8] Bhaskar T, Murai K, Matsui T, Brebu MA, Uddin MA, Muto A, et al. Studies on thermal degradation of acrylonitrile–butadiene–styrene copolymer (ABS-Br) containing brominated flame retardant. Journal of analytical and applied pyrolysis. 2003;70:369-81.
  • [9] Brebu M, Bhaskar T, Murai K, Muto A, Sakata Y, Uddin MA. The individual and cumulative effect of brominated flame retardant and polyvinylchloride (PVC) on thermal degradation of acrylonitrile–butadiene–styrene (ABS) copolymer. Chemosphere. 2004;56:433-40.
  • [10] Dudek P, Raźniak A, Lis B. Rapid prototyping methods for the manufacture of fuel cells. E3S Web of Conferences: EDP Sciences; 2016. p. 00127.
  • [11] Manzanares Palenzuela CL, Novotný F, Krupička P, Sofer Zk, Pumera M. 3D-Printed Graphene/Polylactic Acid Electrodes Promise High Sensitivity in Electroanalysis. Analytical chemistry. 2018;90:5753-7.[12] Vernardou D, Vasilopoulos K, Kenanakis G. 3D printed graphene-based electrodes with high electrochemical performance. Applied Physics A. 2017;123:623.
  • [13] Jaksic NI, Desai PD. Characterization of resistors created by fused filament fabrication using electrically-conductive filament. Procedia Manufacturing. 2018;17:37-44.
  • [14] Macdonald E, Salas R, Espalin D, Perez M, Aguilera E, Muse D, et al. 3D printing for the rapid prototyping of structural electronics. IEEE access. 2014;2:234-42.
  • [15] Sochol RD, Sweet E, Glick CC, Wu S-Y, Yang C, Restaino M, et al. 3D printed microfluidics and microelectronics. Microelectronic Engineering. 2018;189:52-68.
  • [16] Yang Y, Chen Z, Song X, Zhu B, Hsiai T, Wu P-I, et al. Three dimensional printing of high dielectric capacitor using projection based stereolithography method. Nano Energy. 2016;22:414-21.
  • [17] Zhou X, Wang Y, Liu X, Liang Z, Jin H. Electrodeposition Kinetics of Ni/Nano-Y2O3 Composite Coatings. Metals. 2018;8:669.
  • [18] Li G, Gu C, Zhu W, Wang X, Yuan X, Cui Z, et al. Hydrogen production from methanol decomposition using Cu-Al spinel catalysts. Journal of Cleaner Production. 2018;183:415-23.
  • [19] Hüner B, Farsak M, Telli E. A new catalyst of AlCu@ ZnO for hydrogen evolution reaction. International Journal of Hydrogen Energy. 2018;43:7381-7.
  • [20] Wu G, Li N, Wang DL, Zhou DR, Xu BQ, Mitsuo K. Effect of α-Al2O3 particles on the electrochemical codeposition of Co–Ni alloys from sulfamate electrolytes. Materials chemistry and physics. 2004;87:411-9.
  • [21] Zhou X, Wang Y, Liang Z, Jin H. Electrochemical Deposition and Nucleation/Growth Mechanism of Ni–Co–Y2O3 Multiple Coatings. Materials. 2018;11:1124.

EFFECT OF CU COATING ON THE PHYSICAL AND ELECTROCHEMICAL PROPERTIES OF CONDUCTIVE PLA FILAMENT

Yıl 2019, Cilt: 3 Sayı: 2, 128 - 136, 31.08.2019

Öz

3D printing, also known as additive manufacturing (AM), is a new technology that allows to design and production of objects or functional devices in a single process. 3D technology has expanded its ability to utilize as scientific research and medical application, recently. As this technology becomes more widespread, 3D printing systems become more affordable. Especially, the 3D printing method has been used to perform electrodes production for electrochemical applications in the last five years. Commonly known 3D printing filaments are polylactic acid (PLA) or acrylonitrile butadiene styrene (ABS). Thanks to these conductive materials, it is possible to modify their material properties to enhance conductivity or other specifications. In this study, investigation of the electrochemical performance of the conductive PLA is conducted by electroplating of Cu on the surface. In the constant voltage value, current density value of Cu coated electrode is increased three times. Moreover, the usability of conductive PLA as an electrical circuit element or electrochemical energy conversion electrode is investigated. According to the obtained results, in LSV measurements, uncoated PLA and Cu coated PLA has a maximum current of 0.9A and 2.8A at a constant voltage, respectively. In the CV measurement, kinetic performance and electrical conductivity properties are improved in Cu coated PLA sample. In CV measurements, for different scan rate between 50 mV to 200mV is observed that the current value of Cu coated PLA is increased for all measurements. In Cu coated PLA, significant improvement in conductivity is obtained in Electrochemical Impedance Spectroscopy Analysis (EIS).

Kaynakça

  • [1] Ambrosi A, Moo JGS, Pumera M. Helical 3D‐Printed Metal Electrodes as Custom‐Shaped 3D Platform for Electrochemical Devices. Advanced Functional Materials. 2016;26:698-703.
  • [2] Cheng TS, Nasir MZM, Ambrosi A, Pumera M. 3D-printed metal electrodes for electrochemical detection of phenols. Applied Materials Today. 2017;9:212-9.
  • [3] Browne MP, Novotný F, Sofer Zk, Pumera M. 3D Printed Graphene Electrodes’ Electrochemical Activation. ACS applied materials & interfaces. 2018.
  • [4] Kaya MF, Demir N, Albawabiji MS, Taş M. Investigation of alkaline water electrolysis performance for different cost effective electrodes under magnetic field. International Journal of Hydrogen Energy. 2017;42:17583-92.
  • [5] Huang Y, Kormakov S, He X, Gao X, Zheng X, Liu Y, et al. Conductive Polymer Composites from Renewable Resources: An Overview of Preparation, Properties, and Applications. Polymers. 2019;11:187.
  • [6] Yang S, Castilleja JR, Barrera E, Lozano K. Thermal analysis of an acrylonitrile–butadiene–styrene/SWNT composite. Polymer Degradation and Stability. 2004;83:383-8.
  • [7] Yousefi M, Gholamian F, Ghanbari D, Salavati-Niasari M. Polymeric nanocomposite materials: preparation and characterization of star-shaped PbS nanocrystals and their influence on the thermal stability of acrylonitrile–butadiene–styrene (ABS) copolymer. Polyhedron. 2011;30:1055-60.
  • [8] Bhaskar T, Murai K, Matsui T, Brebu MA, Uddin MA, Muto A, et al. Studies on thermal degradation of acrylonitrile–butadiene–styrene copolymer (ABS-Br) containing brominated flame retardant. Journal of analytical and applied pyrolysis. 2003;70:369-81.
  • [9] Brebu M, Bhaskar T, Murai K, Muto A, Sakata Y, Uddin MA. The individual and cumulative effect of brominated flame retardant and polyvinylchloride (PVC) on thermal degradation of acrylonitrile–butadiene–styrene (ABS) copolymer. Chemosphere. 2004;56:433-40.
  • [10] Dudek P, Raźniak A, Lis B. Rapid prototyping methods for the manufacture of fuel cells. E3S Web of Conferences: EDP Sciences; 2016. p. 00127.
  • [11] Manzanares Palenzuela CL, Novotný F, Krupička P, Sofer Zk, Pumera M. 3D-Printed Graphene/Polylactic Acid Electrodes Promise High Sensitivity in Electroanalysis. Analytical chemistry. 2018;90:5753-7.[12] Vernardou D, Vasilopoulos K, Kenanakis G. 3D printed graphene-based electrodes with high electrochemical performance. Applied Physics A. 2017;123:623.
  • [13] Jaksic NI, Desai PD. Characterization of resistors created by fused filament fabrication using electrically-conductive filament. Procedia Manufacturing. 2018;17:37-44.
  • [14] Macdonald E, Salas R, Espalin D, Perez M, Aguilera E, Muse D, et al. 3D printing for the rapid prototyping of structural electronics. IEEE access. 2014;2:234-42.
  • [15] Sochol RD, Sweet E, Glick CC, Wu S-Y, Yang C, Restaino M, et al. 3D printed microfluidics and microelectronics. Microelectronic Engineering. 2018;189:52-68.
  • [16] Yang Y, Chen Z, Song X, Zhu B, Hsiai T, Wu P-I, et al. Three dimensional printing of high dielectric capacitor using projection based stereolithography method. Nano Energy. 2016;22:414-21.
  • [17] Zhou X, Wang Y, Liu X, Liang Z, Jin H. Electrodeposition Kinetics of Ni/Nano-Y2O3 Composite Coatings. Metals. 2018;8:669.
  • [18] Li G, Gu C, Zhu W, Wang X, Yuan X, Cui Z, et al. Hydrogen production from methanol decomposition using Cu-Al spinel catalysts. Journal of Cleaner Production. 2018;183:415-23.
  • [19] Hüner B, Farsak M, Telli E. A new catalyst of AlCu@ ZnO for hydrogen evolution reaction. International Journal of Hydrogen Energy. 2018;43:7381-7.
  • [20] Wu G, Li N, Wang DL, Zhou DR, Xu BQ, Mitsuo K. Effect of α-Al2O3 particles on the electrochemical codeposition of Co–Ni alloys from sulfamate electrolytes. Materials chemistry and physics. 2004;87:411-9.
  • [21] Zhou X, Wang Y, Liang Z, Jin H. Electrochemical Deposition and Nucleation/Growth Mechanism of Ni–Co–Y2O3 Multiple Coatings. Materials. 2018;11:1124.
Toplam 20 adet kaynakça vardır.

Ayrıntılar

Birincil Dil İngilizce
Konular Makine Mühendisliği
Bölüm Araştırma Makalesi
Yazarlar

Mehmet Fatih Kaya

Nesrin Kayataş Demir

Bulut Hüner

Recep Uğur Özcan Bu kişi benim

Yayımlanma Tarihi 31 Ağustos 2019
Gönderilme Tarihi 3 Haziran 2019
Yayımlandığı Sayı Yıl 2019 Cilt: 3 Sayı: 2

Kaynak Göster

APA Kaya, M. F., Kayataş Demir, N., Hüner, B., Özcan, R. U. (2019). EFFECT OF CU COATING ON THE PHYSICAL AND ELECTROCHEMICAL PROPERTIES OF CONDUCTIVE PLA FILAMENT. International Journal of 3D Printing Technologies and Digital Industry, 3(2), 128-136.
AMA Kaya MF, Kayataş Demir N, Hüner B, Özcan RU. EFFECT OF CU COATING ON THE PHYSICAL AND ELECTROCHEMICAL PROPERTIES OF CONDUCTIVE PLA FILAMENT. IJ3DPTDI. Ağustos 2019;3(2):128-136.
Chicago Kaya, Mehmet Fatih, Nesrin Kayataş Demir, Bulut Hüner, ve Recep Uğur Özcan. “EFFECT OF CU COATING ON THE PHYSICAL AND ELECTROCHEMICAL PROPERTIES OF CONDUCTIVE PLA FILAMENT”. International Journal of 3D Printing Technologies and Digital Industry 3, sy. 2 (Ağustos 2019): 128-36.
EndNote Kaya MF, Kayataş Demir N, Hüner B, Özcan RU (01 Ağustos 2019) EFFECT OF CU COATING ON THE PHYSICAL AND ELECTROCHEMICAL PROPERTIES OF CONDUCTIVE PLA FILAMENT. International Journal of 3D Printing Technologies and Digital Industry 3 2 128–136.
IEEE M. F. Kaya, N. Kayataş Demir, B. Hüner, ve R. U. Özcan, “EFFECT OF CU COATING ON THE PHYSICAL AND ELECTROCHEMICAL PROPERTIES OF CONDUCTIVE PLA FILAMENT”, IJ3DPTDI, c. 3, sy. 2, ss. 128–136, 2019.
ISNAD Kaya, Mehmet Fatih vd. “EFFECT OF CU COATING ON THE PHYSICAL AND ELECTROCHEMICAL PROPERTIES OF CONDUCTIVE PLA FILAMENT”. International Journal of 3D Printing Technologies and Digital Industry 3/2 (Ağustos 2019), 128-136.
JAMA Kaya MF, Kayataş Demir N, Hüner B, Özcan RU. EFFECT OF CU COATING ON THE PHYSICAL AND ELECTROCHEMICAL PROPERTIES OF CONDUCTIVE PLA FILAMENT. IJ3DPTDI. 2019;3:128–136.
MLA Kaya, Mehmet Fatih vd. “EFFECT OF CU COATING ON THE PHYSICAL AND ELECTROCHEMICAL PROPERTIES OF CONDUCTIVE PLA FILAMENT”. International Journal of 3D Printing Technologies and Digital Industry, c. 3, sy. 2, 2019, ss. 128-36.
Vancouver Kaya MF, Kayataş Demir N, Hüner B, Özcan RU. EFFECT OF CU COATING ON THE PHYSICAL AND ELECTROCHEMICAL PROPERTIES OF CONDUCTIVE PLA FILAMENT. IJ3DPTDI. 2019;3(2):128-36.

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