Araştırma Makalesi
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Yıl 2019, Cilt: 15 Sayı: 4, 351 - 356, 30.12.2019
https://doi.org/10.18466/cbayarfbe.632188

Öz

Kaynakça

  • Referans1. Günnaz, S, Özdemir, N, Dayan, S, Dayan, O, Çetinkaya, B, 2011. Synthesis of Ruthenium(II) Complexes Containing Tridentate Triamine (′N ͡N ͡N′) and Bidentate Diamine Ligands (N ͡N′): as Catalysts for Transfer Hydrogenation of Ketones, Organometallics, 30(15): 4165-4173.
  • Referans2. Haneda, S, Adachi, Y, Hayashi, M. 2009. Copper(I)-2-(2′-pyridyl)benzimidazole catalyzed N-arylation of indoles, Tetrahedron, 65(50): 10459-10462.
  • Referans3. Haneda, S, Gan, Z, Eda, K, Hayashi, M. 2007. Ligand Effects of 2-(2-Pyridyl)benzazole−Pd Complexes on the X-ray Crystallographic Structures, 1H NMR Spectra, and Catalytic Activities in Mizoroki−Heck Reactions, Organometallics, 26(26): 6551-6555.
  • Referans4. Done, M, C, Ruther, T, Cavell, K, J, Kilner, M, Peacock, E. J, Braussaud, N, Skelton, B, W, White, A, J. 2000. Novel cationic and neutral Pd(II) complexes bearing imidazole based chelate ligands: synthesis, structural characterisation and catalytic behaviour, J. Organomet. Chem., 607(1): 78-92.
  • Referans5. Zhao, X, Liu, D, Li, Y, Cui, G. 2018. Two 3D cadmium (II) coordination polymers modulated by flexible bis(benzimidazole) ligands displaying high photocatalytic activities for degradation of methylene blue and methyl orange, Polyhedron, 156(1): 200-207.
  • Referans6. Aksenov, A, V, Smirnov, A, N, Aksenov N, A, Bijieva, A, S, Aksenova, I, V, Rubin, M. 2015. Benzimidazoles and benzoxazoles via the nucleophilic addition of anilines to nitroalkanes, Org. Biomol. Chem., 13(14): 4289-4295.
  • Referans7. Zhang, D, Jiang, X, Yang, H, Martinez, A, Feng, M, Donga, Z, Gao, G. 2013. Acridine-based macrocyclic fluorescent sensors: self-assembly behavior characterized by crystal structures and a tunable bathochromic-shift in emission induced by H2PO4− via adjusting the ring size and rigidity, Org. Biomol. Chem., 11(20): 3375-3381.
  • Referans8. Liu, Q, X, Wei, Q, Zhao, X, J, Wang, H, Li, S, J, Wang, X, G. 2013. Cobalt(II), copper(II), zinc(II) and cadmium(II) complexes based on dibenzimidazolyl bidentate ligands with alkanyl linkers: crystal structure, weak interactions and conformations, Dalton Trans., 42(16): 5902-5915.
  • Referans9. Iaroshenko, V, O, Ostrovskyi, D, Miliutina, M, Maalik, A, Villinger, A, Tolmachev, A, Volochnyuk, D, M, Langer, P. 2012. Design and Synthesis of Polycyclic Imidazole‐Containing N‐ Heterocycles based on C-H Activation/Cyclization Reactions, Adv. Synth. Catal., 354(13): 2495-2503.
  • Referans10. Kucukbay, H, Yilmaz, U, Sireci, N, Onganer, A, N. 2011. Synthesis and antimicrobial activities of some bridged bis-benzimidazole derivatives, Turk. J. Chem., 35(4): 561-571.
  • Referans11. Wang, D, E, Deng, K, J, Lv, K, L, Wang, C, G, Wen, L, L, Li, D, F. 2009. Structures, photoluminescence and photocatalytic properties of three new metal–organic frameworks based on non-rigid long bridges, CrystEngComm, 11(7): 1442-1450.
  • Referans12. Wong, W, W, H, Vickers, M, S, Cowley, A, R, Paul, R, L, Beer, P, D. 2005. Tetrakis(imidazolium) macrocyclic receptors for anion binding, Org. Biomol. Chem., 3(23): 4201-4208.
  • Referans13. Ma, J, F, Liu, J, F, Liu, Y, C, Xing, Y, Jia, H, Q, Lin, Y, H. 2000. Two new coordination polymers of Co(II) with 1,1′-(1,4-butanediyl)bis(benzimidazole), New J. Chem., 24(10): 759-763.
  • Referans14. Shi, Z, Thummel, R, P. 1995. N,N'-Bridged Derivatives of 2,2'-Bibenzimidazole, J. Org. Chem., 60(18): 5935-5945.
  • Referans15. Shi, Z, Thummel, R, P. 1995. Bridged dibenzimidazolinylidenes as new derivatives of tetraaminoethylene, Tetrahedron Lett., 36(16): 2741-2744.
  • Referans16. Dayan, O, Özdemir, N, Şerbetci, Z, Dinçer, M, Çetinkaya, B, Büyükgüngör, O. 2012. Synthesis and catalytic activity of ruthenium(II) complexes containing pyridine-based tridentate triamines (NNN) and pyridine carboxylate ligands (NO), Inorg. Chim. Acta, 392(1): 246-253.
  • Referans17. Noyori, R, Hashiguchi, S. 1997. Asymmetric Transfer Hydrogenation Catalyzed by Chiral Ruthenium Complexes, Acc. Chem. Res., 30(2): 97-102.
  • Referans18. Gao, J, X, Ikariya, T, Noyori, R. 1996. A Ruthenium(II) Complex with a C2-Symmetric Diphosphine/Diamine Tetradentate Ligand for Asymmetric Transfer Hydrogenation of Aromatic Ketones, Organometallics, 15(4): 1087-1089.

Synthesis and catalytic activities of bimetallic Ru (II) arene complexes bearing bis-benzimidazoles

Yıl 2019, Cilt: 15 Sayı: 4, 351 - 356, 30.12.2019
https://doi.org/10.18466/cbayarfbe.632188

Öz

In this study, bis-benzimidazole
ligands (1a-d) were synthesized using linker groups and they were
evaluated as catalyst generated in situ
from
[RuCl2(p-cymene)]2 for transfer hydrogenation (TH) of
acetophenone. The bimetallic Ru (II) arene complex (2b) synthesized from
ligand 1b which showed the best activity among the ligands in the catalytic
TH reaction. The obtained ligands and 2b complex were characterized by 1H-
and 13C-NMR, elemental analysis and IR spectroscopy. The catalytic
activities of complexes having different chain lengths and Y (CH3 or
H) groups were compared. The highest conversion (99%) was obtained with 2b.

0000-0002-7422-6593

Kaynakça

  • Referans1. Günnaz, S, Özdemir, N, Dayan, S, Dayan, O, Çetinkaya, B, 2011. Synthesis of Ruthenium(II) Complexes Containing Tridentate Triamine (′N ͡N ͡N′) and Bidentate Diamine Ligands (N ͡N′): as Catalysts for Transfer Hydrogenation of Ketones, Organometallics, 30(15): 4165-4173.
  • Referans2. Haneda, S, Adachi, Y, Hayashi, M. 2009. Copper(I)-2-(2′-pyridyl)benzimidazole catalyzed N-arylation of indoles, Tetrahedron, 65(50): 10459-10462.
  • Referans3. Haneda, S, Gan, Z, Eda, K, Hayashi, M. 2007. Ligand Effects of 2-(2-Pyridyl)benzazole−Pd Complexes on the X-ray Crystallographic Structures, 1H NMR Spectra, and Catalytic Activities in Mizoroki−Heck Reactions, Organometallics, 26(26): 6551-6555.
  • Referans4. Done, M, C, Ruther, T, Cavell, K, J, Kilner, M, Peacock, E. J, Braussaud, N, Skelton, B, W, White, A, J. 2000. Novel cationic and neutral Pd(II) complexes bearing imidazole based chelate ligands: synthesis, structural characterisation and catalytic behaviour, J. Organomet. Chem., 607(1): 78-92.
  • Referans5. Zhao, X, Liu, D, Li, Y, Cui, G. 2018. Two 3D cadmium (II) coordination polymers modulated by flexible bis(benzimidazole) ligands displaying high photocatalytic activities for degradation of methylene blue and methyl orange, Polyhedron, 156(1): 200-207.
  • Referans6. Aksenov, A, V, Smirnov, A, N, Aksenov N, A, Bijieva, A, S, Aksenova, I, V, Rubin, M. 2015. Benzimidazoles and benzoxazoles via the nucleophilic addition of anilines to nitroalkanes, Org. Biomol. Chem., 13(14): 4289-4295.
  • Referans7. Zhang, D, Jiang, X, Yang, H, Martinez, A, Feng, M, Donga, Z, Gao, G. 2013. Acridine-based macrocyclic fluorescent sensors: self-assembly behavior characterized by crystal structures and a tunable bathochromic-shift in emission induced by H2PO4− via adjusting the ring size and rigidity, Org. Biomol. Chem., 11(20): 3375-3381.
  • Referans8. Liu, Q, X, Wei, Q, Zhao, X, J, Wang, H, Li, S, J, Wang, X, G. 2013. Cobalt(II), copper(II), zinc(II) and cadmium(II) complexes based on dibenzimidazolyl bidentate ligands with alkanyl linkers: crystal structure, weak interactions and conformations, Dalton Trans., 42(16): 5902-5915.
  • Referans9. Iaroshenko, V, O, Ostrovskyi, D, Miliutina, M, Maalik, A, Villinger, A, Tolmachev, A, Volochnyuk, D, M, Langer, P. 2012. Design and Synthesis of Polycyclic Imidazole‐Containing N‐ Heterocycles based on C-H Activation/Cyclization Reactions, Adv. Synth. Catal., 354(13): 2495-2503.
  • Referans10. Kucukbay, H, Yilmaz, U, Sireci, N, Onganer, A, N. 2011. Synthesis and antimicrobial activities of some bridged bis-benzimidazole derivatives, Turk. J. Chem., 35(4): 561-571.
  • Referans11. Wang, D, E, Deng, K, J, Lv, K, L, Wang, C, G, Wen, L, L, Li, D, F. 2009. Structures, photoluminescence and photocatalytic properties of three new metal–organic frameworks based on non-rigid long bridges, CrystEngComm, 11(7): 1442-1450.
  • Referans12. Wong, W, W, H, Vickers, M, S, Cowley, A, R, Paul, R, L, Beer, P, D. 2005. Tetrakis(imidazolium) macrocyclic receptors for anion binding, Org. Biomol. Chem., 3(23): 4201-4208.
  • Referans13. Ma, J, F, Liu, J, F, Liu, Y, C, Xing, Y, Jia, H, Q, Lin, Y, H. 2000. Two new coordination polymers of Co(II) with 1,1′-(1,4-butanediyl)bis(benzimidazole), New J. Chem., 24(10): 759-763.
  • Referans14. Shi, Z, Thummel, R, P. 1995. N,N'-Bridged Derivatives of 2,2'-Bibenzimidazole, J. Org. Chem., 60(18): 5935-5945.
  • Referans15. Shi, Z, Thummel, R, P. 1995. Bridged dibenzimidazolinylidenes as new derivatives of tetraaminoethylene, Tetrahedron Lett., 36(16): 2741-2744.
  • Referans16. Dayan, O, Özdemir, N, Şerbetci, Z, Dinçer, M, Çetinkaya, B, Büyükgüngör, O. 2012. Synthesis and catalytic activity of ruthenium(II) complexes containing pyridine-based tridentate triamines (NNN) and pyridine carboxylate ligands (NO), Inorg. Chim. Acta, 392(1): 246-253.
  • Referans17. Noyori, R, Hashiguchi, S. 1997. Asymmetric Transfer Hydrogenation Catalyzed by Chiral Ruthenium Complexes, Acc. Chem. Res., 30(2): 97-102.
  • Referans18. Gao, J, X, Ikariya, T, Noyori, R. 1996. A Ruthenium(II) Complex with a C2-Symmetric Diphosphine/Diamine Tetradentate Ligand for Asymmetric Transfer Hydrogenation of Aromatic Ketones, Organometallics, 15(4): 1087-1089.
Toplam 18 adet kaynakça vardır.

Ayrıntılar

Birincil Dil İngilizce
Bölüm Makaleler
Yazarlar

Salih Günnaz 0000-0002-7422-6593

Yayımlanma Tarihi 30 Aralık 2019
Yayımlandığı Sayı Yıl 2019 Cilt: 15 Sayı: 4

Kaynak Göster

APA Günnaz, S. (2019). Synthesis and catalytic activities of bimetallic Ru (II) arene complexes bearing bis-benzimidazoles. Celal Bayar University Journal of Science, 15(4), 351-356. https://doi.org/10.18466/cbayarfbe.632188
AMA Günnaz S. Synthesis and catalytic activities of bimetallic Ru (II) arene complexes bearing bis-benzimidazoles. CBUJOS. Aralık 2019;15(4):351-356. doi:10.18466/cbayarfbe.632188
Chicago Günnaz, Salih. “Synthesis and Catalytic Activities of Bimetallic Ru (II) Arene Complexes Bearing Bis-Benzimidazoles”. Celal Bayar University Journal of Science 15, sy. 4 (Aralık 2019): 351-56. https://doi.org/10.18466/cbayarfbe.632188.
EndNote Günnaz S (01 Aralık 2019) Synthesis and catalytic activities of bimetallic Ru (II) arene complexes bearing bis-benzimidazoles. Celal Bayar University Journal of Science 15 4 351–356.
IEEE S. Günnaz, “Synthesis and catalytic activities of bimetallic Ru (II) arene complexes bearing bis-benzimidazoles”, CBUJOS, c. 15, sy. 4, ss. 351–356, 2019, doi: 10.18466/cbayarfbe.632188.
ISNAD Günnaz, Salih. “Synthesis and Catalytic Activities of Bimetallic Ru (II) Arene Complexes Bearing Bis-Benzimidazoles”. Celal Bayar University Journal of Science 15/4 (Aralık 2019), 351-356. https://doi.org/10.18466/cbayarfbe.632188.
JAMA Günnaz S. Synthesis and catalytic activities of bimetallic Ru (II) arene complexes bearing bis-benzimidazoles. CBUJOS. 2019;15:351–356.
MLA Günnaz, Salih. “Synthesis and Catalytic Activities of Bimetallic Ru (II) Arene Complexes Bearing Bis-Benzimidazoles”. Celal Bayar University Journal of Science, c. 15, sy. 4, 2019, ss. 351-6, doi:10.18466/cbayarfbe.632188.
Vancouver Günnaz S. Synthesis and catalytic activities of bimetallic Ru (II) arene complexes bearing bis-benzimidazoles. CBUJOS. 2019;15(4):351-6.