Öz
Bu çalışmada endüstriyel
olarak sıklıkla kullanılan 304L kalite çelik altlıklar üzerine, üstün katı
yağlayıcılık ve mekanik mukavemet özellikleri gösteren hegzagonal bor nitrür
(hBN) nano partikülleriyle desteklenmiş nikel-bor (Nİ-B) alaşım matrisli
kompozit kaplamalar galvanostatik elektrodepolama yoluyla kaplanmıştır. Çalışmada
Tergitol™ yüzey aktif madde (sürfaktan) olarak kullanılmış ve bu yüzey aktif
maddenin depolama süspansiyonundaki konsantrasyonunun kaplamaların yapısal,
morfolojik, mikrosertlik, ve korozyon koruma özellikleri üzerine etkisi
sırasıyla XRD, FE-SEM, Vickers mikrosertlik, potansiyodinamik polarizasyon ve elektrokimyasal
empedans spektroskopisi kullanılarak incelenmiştir. Sonuç olarak, Tergitol'ün
metal matrisli kompozit kaplamaların elektrodepolanması için etkili bir yüzey
aktif madde olarak kullanılabileceği sonucuna varılmıştır.
Anahtar Kelimeler
Elektrodepolama Ni-B; Mikrosertlik Yüzey Aktif Madde Korozyon
Destekleyen Kurum
Mustafa Kemal Üniversitesi Bilimsel Araştırma Projeleri Birimi
Proje Numarası
19 M 020
Teşekkür
Mustafa Kemal Üniversitesi Bilimsel Araştırma Projeleri Birimi'ne projeyi finanse ettiği için teşekkür ederim.
Kaynakça
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- Gyawali, G., Hamal, K., Joshi, B., Rajbhandari, A., & Wohn Lee, S. (2014). Microstructural and electrochemical analysis of Ni–SiC composite coatings prepared in presence of additives. Materials Letters, 126, 228-231.
- Kumaraguru, S., & Mohan, S. (2018). Study of Ni-Bi2O3-CeO2 composite coatings: Hierarchical microstructure and augmented microhardness for surface engineering application. Surface & Coatings Technology, 349, 567-575.
- Kwon, H. B., Kim, K., Ahn, H. R., & Kim, Y. J. (2017). Electrodeposition and Characterization of Nanocrystalline Ni-B with Low Boron Content for MEMS Applications. Sensors and Materials, 29(3), 225-234.
- Li, B. S., Huan, Y. X., Luo, H., & Zhang, W. W. (2019). Electrodeposition and properties of Ni-B/SiC nanocomposite coatings. Surface Engineering, 35(2), 110-120.Maharana, H. S., & Basu, A. (2018). Effects of Different Surfactants on Structural, Tribological and Electrical Properties of Pulsed Electro-Codeposited Cu-ZrO2 Composite Coatings. Journal of Materials Engineering and Performance, 27(4), 1854-1865.
- Mardani, R., Asrar, A., & Ershadifar, H. (2018). The effect of surfactant on the structure, composition and magnetic properties of electrodeposited CoNiFe /Cu microwire. Materials Chemistry and Physics, 211, 160-167.
- Matsui, I., Omura, N., Yamamoto, T., & Takigawa, Y. (2018). Electrodeposition with intermittent addition of trimethylamine borane to produce ductile bulk nanocrystalline Ni-B alloys. Surface & Coatings Technology, 337, 411-417.
- Mehr, M. S., Akbari, A., & Damerchi, E. (2019). Electrodeposited Ni-B/SiC micro- and nano-composite coatings: A comparative study. Journal of Alloys and Compounds, 782, 477-487.
- Mirzamohammadi, S., Khorsand, H., & Aliofkhazraei, M. (2017). Effect of different organic solvents on electrodeposition and wear behavior of Ni-alumina nanocomposite coatings. Surface & Coatings Technology, 313, 202-213.
- Nam, D.-H., Kim, T.-H., Hong, K.-S., & Kwon, H.-S. (2014). Template-Free Electrochemical Synthesis of Sn Nanofibers as High-Performance Anode Materials for Na-Ion Batteries. ACS Nano, 8(11), 11824-11835.
- Offoiach, R., Lekka, M., Lanzutti, A., Martinez-Nogues, V., Vega, J. M., Garcia-Lecina, E., & Fedrizzi, L. (2019). Tribocorrosion study of Ni/B electrodeposits with low B content. Surface & Coatings Technology, 369, 1-15.
- Ogihara, H., Miyamoto, K., Udagawa, K., & Saji, T. (2011). Electrodeposition of Super Hard Ni-B/Diamond Composite Coatings. Chemistry Letters, 40(10), 1072-1073.Unal, E., & Karahan, I. H. (2018). Effects of ultrasonic agitation prior to deposition and additives in the bath on electrodeposited Ni-B/hBN composite coatings. Journal of Alloys and Compounds, 763, 329-341.
- Wang, Z. C., Yu, L., Jia, F., & Song, G. L. (2012). Effect of Additives and Heat Treatment on the Formation and Performance of Electroless Nickel-Boron Plating on AZ91D Mg Alloy. Journal of the Electrochemical Society, 159(7), D406-D412.
- Yousif, A., Kumar, V., Jafer, R. M., & Swart, H. C. (2017). The effect of different annealing temperatures on the structure and luminescence properties of Y2O3:Bi3+ thin film fabricated by RF magnetron sputtering. Applied Surface Science, 424, 407-411.
- Zhang, R. Y., Li, Z. L., Yu, X., & Cui, G. (2019). Characterisation and properties of Ni-W-Y2O3-ZrO2 nanocomposite coating. Surface Engineering, 35(7), 578-587.Zhang, Y. H., Feng, L., & Qiu, W. (2019). Effects of glycine on mechanical properties and microstructure of diamond-reinforced Ni nanocomposite coatings. Journal of Materials Science, 54(13), 9507-9522.
- Zhu, H. M., Geng, S. J., Chen, G., & Wang, F. H. (2019). Ni-Mn3O4 Composite Coating by Electrophoresis/Electrodeposition for Metallic Interconnects Applications. Journal of the Electrochemical Society, 166(6), F423-F430.
Ayrıntılar
| Birincil Dil | Türkçe |
|---|---|
| Konular | Mühendislik |
| Bölüm | Makaleler |
| Yazarlar | |
| Proje Numarası | 19 M 020 |
| Yayımlanma Tarihi | 17 Mart 2020 |
| Gönderilme Tarihi | 9 Temmuz 2019 |
| Yayımlandığı Sayı | Yıl 2020 Cilt: 20 Sayı: 1 |
