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Green Preparation of Multiwalled Carbon Nanotubes Supported Pd and Cu Nanoparticles with Novel Vic-dioxime Metal Complexes

Year 2018, Volume: 5 Issue: 3, 1249 - 1256, 01.09.2018
https://doi.org/10.18596/jotcsa.381305

Abstract

The preparation of multi-walled
carbon nanotubes (MW-CNTs) supported Cu and Pd nanoparticles on utilizing a
supercritical carbon dioxide deposition method were
investigated. Novel vic-dioxime
complexes of Cu(II) and Pd(II) were used as metallic precursors. The ligand
used in these precursors were 4-(trifluoromethyl)aniline-vic-dioxide. Ligand and metal complexes were synthesized and identified
with various analyses method including 1H and 19F NMR,
FT-IR, UV-Vis, elemental analysis and magnetic susceptibility. MW-CNTs
supported Pd and Cu nanoparticles were characterized by high-resolution
transmission electron microscopy (HR_TEM), X-ray diffraction (XRD) and scanning
electron microscopy with EDX (SEM_EDX). SEM_EDX and HR_TEM micrographs showed a
homogenous distribution of reasonably well-dispersed
Cu and Pd nanoparticles on the support. The nature and crystallinity of the
nano metal particles were confirmed using XRD. Crystallite sizes ranged from
7-20 nm for palladium and 20-30 nm for copper. This study demonstrated that
these oxime complexes are suitable precursors for the preparation of supported
nanoparticles using a supercritical carbon dioxide deposition method. 

References

  • 1. Ulusal F, Darendeli B, Erünal E, Eğitmen A, Güzel B. Supercritical carbon dioxide deposition of γ-Alumina supported Pd nanocatalysts with new precursors and using on Suzuki-Miyaura coupling reactions. The Journal of Supercritical Fluids. 2017;127:111–120.
  • 2. Cangul B, Zhang LC, Aindow M, Erkey C. Preparation of carbon black supported Pd, Pt and Pd–Pt nanoparticles using supercritical CO2 deposition. The Journal of Supercritical Fluids. 2009; 50: 82–90.
  • 3. Zhang Y, Erkey C. Preparation of supported metallic nanoparticles using supercritical fluids: A review. The Journal of Supercritical Fluids. 2006;38:252–267.
  • 4. Daoush WM, Lim BK, Mo CB, Nam DH, Hong SH. Electrical and mechanical properties of carbon nanotube reinforced copper nanocomposites fabricated by electroless deposition process. Materials Science and Engineering: A. 2009;513–514:247–253.
  • 5. Park PW, Ledford JS. The influence of surface structure on the catalytic activity of alumina supported copper oxide catalysts. Oxidation of carbon monoxide and methane. Applied Catalysis B: Environmental. 1998;15:221–231.
  • 6. Rather S, Zacharia R, Hwang SW, Naik M, Nahm KS. Hydrogen uptake of palladium-embedded MW-CNTs produced by impregnation and condensed phase reduction method. Chemical Physics Letters. 2007;441:261–267.
  • 7. Lam F, Hu X. A new system design for the preparation of copper/activated carbon catalyst by metal-organic chemical vapor deposition method. Chemical Engineering Science. 2003;58:687 – 695.
  • 8. Ulusal H, Fındıkkıran G, Demirkol O, Akbaşlar D, Giray ES. Supercritical diethylether: A novel solvent for the synthesis of aryl-3,4,5,6,7,9-hexahydroxanthene-1,8-diones. The Journal of Supercritical Fluids. 2015;105:146–150.
  • 9. Zhang Y, Erkey C. Preparation of supported metallic nanoparticles using supercritical fluids: A review. The Journal of Supercritical Fluids. 2006;38:252–267.
  • 10. Dobrovolna Z, Kacer P, Cerveny L. Competitive hydrogenation in alkene–alkyne–diene systems with palladium and platinum catalysts. Journal of Molecular Catalysis A: Chemical. 1998;130:279-284.
  • 11. Ye XR, Lin Y, Whang C, Engelhard MH, Wang Y, Wai CM. Supercritical fluid synthesis and characterization of catalytic metal nanoparticles on carbon nanotubes. Journal of Materials Chemistry. 2004;14:908-913.
  • 12. Kim J, Kelly MJ, Lamb HH, Roberts GW, Kiserow D. Characterization of palladium (Pd) on alumina catalysts prepared using liquid carbon dioxide. The Journal of Physical Chemistry C. 2008; 112: 10446–10452.
  • 13. Erünal E, Ulusal F, Aslan MY, Güzel B, Üner D. Enhancement of hydrogen storage capacity of multi-walled carbon nanotubes with palladium doping prepared through supercritical CO2 deposition method. International Journal of Hydrogen Energy. 2018; 43: 10755-1076
  • 14. Yildirim B, Özcan E, Deveci P. New glyoxime derivatives and their transition metal complexes. Russian Journal of Coordination Chemistry. 2007;33:417–421.
  • 15. Teoh WH, Mammucari R, Foster NR. Solubility of organometallic complexes in supercritical carbon dioxide: A review. Journal of Organometallic Chemistry. 2013;724:102-116.
  • 16. Aschenbrenner O, Kemper S, Dahmena N, Schaber K, Dinjus E. Solubility of β-diketonates, cyclopentadienyls, and cyclooctadiene complexes with various metals in supercritical carbon dioxide. Journal of Supercritical Fluids. 2007; 41: 179–186.
  • 17. Guzel B, Avşar G, Çınkır H. Supercritical carbon dioxide-soluble fluorus vic-dioxime ligands and their Ni(II) complexes: synthesis, characterization and solubility properties. Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry. 2007;37:801-804.
  • 18. Ulusal F, Güzel B. Deposition of palladium by the hydrogen assisted on SBA-15 with a new precursor using supercritical carbon dioxide. The Journal of Supercritical Fluids. 2018; 133: 233–238.
  • 19. Cabanas A, Blackburn J, Watkins J. Deposition of Cu films from supercritical fluids using Cu(I) β-diketonate precursors. Microelectronic Engineering. 2002;64:53-61.
  • 20. Ulusal F. Güzel B. Synthesis and Characterization of Novel Pd and Cu vic-dioxime Precursors for Their Supercritical Deposition on Multiwalled Carbon Nanotubes. Journal of the Turkish Chemical Society, Section A: Chemistry. 2018; 5(2): 635-52.
Year 2018, Volume: 5 Issue: 3, 1249 - 1256, 01.09.2018
https://doi.org/10.18596/jotcsa.381305

Abstract

References

  • 1. Ulusal F, Darendeli B, Erünal E, Eğitmen A, Güzel B. Supercritical carbon dioxide deposition of γ-Alumina supported Pd nanocatalysts with new precursors and using on Suzuki-Miyaura coupling reactions. The Journal of Supercritical Fluids. 2017;127:111–120.
  • 2. Cangul B, Zhang LC, Aindow M, Erkey C. Preparation of carbon black supported Pd, Pt and Pd–Pt nanoparticles using supercritical CO2 deposition. The Journal of Supercritical Fluids. 2009; 50: 82–90.
  • 3. Zhang Y, Erkey C. Preparation of supported metallic nanoparticles using supercritical fluids: A review. The Journal of Supercritical Fluids. 2006;38:252–267.
  • 4. Daoush WM, Lim BK, Mo CB, Nam DH, Hong SH. Electrical and mechanical properties of carbon nanotube reinforced copper nanocomposites fabricated by electroless deposition process. Materials Science and Engineering: A. 2009;513–514:247–253.
  • 5. Park PW, Ledford JS. The influence of surface structure on the catalytic activity of alumina supported copper oxide catalysts. Oxidation of carbon monoxide and methane. Applied Catalysis B: Environmental. 1998;15:221–231.
  • 6. Rather S, Zacharia R, Hwang SW, Naik M, Nahm KS. Hydrogen uptake of palladium-embedded MW-CNTs produced by impregnation and condensed phase reduction method. Chemical Physics Letters. 2007;441:261–267.
  • 7. Lam F, Hu X. A new system design for the preparation of copper/activated carbon catalyst by metal-organic chemical vapor deposition method. Chemical Engineering Science. 2003;58:687 – 695.
  • 8. Ulusal H, Fındıkkıran G, Demirkol O, Akbaşlar D, Giray ES. Supercritical diethylether: A novel solvent for the synthesis of aryl-3,4,5,6,7,9-hexahydroxanthene-1,8-diones. The Journal of Supercritical Fluids. 2015;105:146–150.
  • 9. Zhang Y, Erkey C. Preparation of supported metallic nanoparticles using supercritical fluids: A review. The Journal of Supercritical Fluids. 2006;38:252–267.
  • 10. Dobrovolna Z, Kacer P, Cerveny L. Competitive hydrogenation in alkene–alkyne–diene systems with palladium and platinum catalysts. Journal of Molecular Catalysis A: Chemical. 1998;130:279-284.
  • 11. Ye XR, Lin Y, Whang C, Engelhard MH, Wang Y, Wai CM. Supercritical fluid synthesis and characterization of catalytic metal nanoparticles on carbon nanotubes. Journal of Materials Chemistry. 2004;14:908-913.
  • 12. Kim J, Kelly MJ, Lamb HH, Roberts GW, Kiserow D. Characterization of palladium (Pd) on alumina catalysts prepared using liquid carbon dioxide. The Journal of Physical Chemistry C. 2008; 112: 10446–10452.
  • 13. Erünal E, Ulusal F, Aslan MY, Güzel B, Üner D. Enhancement of hydrogen storage capacity of multi-walled carbon nanotubes with palladium doping prepared through supercritical CO2 deposition method. International Journal of Hydrogen Energy. 2018; 43: 10755-1076
  • 14. Yildirim B, Özcan E, Deveci P. New glyoxime derivatives and their transition metal complexes. Russian Journal of Coordination Chemistry. 2007;33:417–421.
  • 15. Teoh WH, Mammucari R, Foster NR. Solubility of organometallic complexes in supercritical carbon dioxide: A review. Journal of Organometallic Chemistry. 2013;724:102-116.
  • 16. Aschenbrenner O, Kemper S, Dahmena N, Schaber K, Dinjus E. Solubility of β-diketonates, cyclopentadienyls, and cyclooctadiene complexes with various metals in supercritical carbon dioxide. Journal of Supercritical Fluids. 2007; 41: 179–186.
  • 17. Guzel B, Avşar G, Çınkır H. Supercritical carbon dioxide-soluble fluorus vic-dioxime ligands and their Ni(II) complexes: synthesis, characterization and solubility properties. Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry. 2007;37:801-804.
  • 18. Ulusal F, Güzel B. Deposition of palladium by the hydrogen assisted on SBA-15 with a new precursor using supercritical carbon dioxide. The Journal of Supercritical Fluids. 2018; 133: 233–238.
  • 19. Cabanas A, Blackburn J, Watkins J. Deposition of Cu films from supercritical fluids using Cu(I) β-diketonate precursors. Microelectronic Engineering. 2002;64:53-61.
  • 20. Ulusal F. Güzel B. Synthesis and Characterization of Novel Pd and Cu vic-dioxime Precursors for Their Supercritical Deposition on Multiwalled Carbon Nanotubes. Journal of the Turkish Chemical Society, Section A: Chemistry. 2018; 5(2): 635-52.
There are 20 citations in total.

Details

Primary Language English
Subjects Chemical Engineering
Journal Section Articles
Authors

Fatma Ulusal 0000-0001-6926-6251

Bilgehan Güzel

Publication Date September 1, 2018
Submission Date January 19, 2018
Acceptance Date November 30, 2018
Published in Issue Year 2018 Volume: 5 Issue: 3

Cite

Vancouver Ulusal F, Güzel B. Green Preparation of Multiwalled Carbon Nanotubes Supported Pd and Cu Nanoparticles with Novel Vic-dioxime Metal Complexes. JOTCSA. 2018;5(3):1249-56.