Synthesis and characterization of new phosphor based MTiO3

N. Kayacı; Serkan Dayan; A. K. Küçük; Nilgün Kalaycıoğlu Özpozan; E. Öztürk; E. Karacaoğlu

doi:10.1501/nuclear_0000000011

Research Article

Synthesis and characterization of new phosphor based MTiO3

Year 2015, Volume: 2 Issue: 2, 31 - 47, 20.06.2015

N. Kayacı Serkan Dayan , A. K. Küçük Nilgün Kalaycıoğlu Özpozan , E. Öztürk E. Karacaoğlu

https://doi.org/10.1501/nuclear_0000000011

Abstract

In this study, new titanate phosphors were synthesized. The Dy3+, Eu3+, Ho3+ rare-earth ions were used as dopants to CaTiO3, SrTiO3, and BaTiO3 host crystals. The optimization of reaction conditions were carried out by thermogravimetry (TG) and differential thermal analysis (DTA) methods. The mixtures to achieve a solid state reaction were heated in porcelain crucibles for preheating process at 600 oC and 800 oC and final heating process at 1000 oC for 16 hours in the open atmosphere. The reaction products were characterized by X-ray powder diffractions (XRD). Surface investigations and elemental analysis were determined by using SEM-EDX instrument.
Photoluminescence spectrophotometer (PL) was used for the observation of the excitation and emission spectra.

Keywords

Perovskite, Luminescence, Phosphors, Solid state synthesis techniques, XRD

References

[1] W.J. Jaffe, R. Cook, H. Jaffe, “Piezoelectric ceramics”, Academic Press, New York (1971).
[2] M.E. Lines, A.M. Glass, “Principles and applications of ferroelectrics and related materials”, Oxford University Press, Oxford (2001).
[3] J.F. Scott, “Applications of modern ferroelectrics”, Science, 315 954–63 (2007).
[4] Y. Yang, X.H. Wang, C.K. Sun, L.T. Li, “Photoluminescence of high aspect-ratio PbTiO3 nanotube arrays”, J. Am. Ceram. Soc., 91 3820–2 (2008).
[5] G. Nenartaviciene, K. Tonsuaadu, D. Jasaitis, A. Beganskiene, A.Kareiva, “Preparation and characterization of superconducting YBa2(Cu1-xCrx)4O8 oxides by thermal analysis”, J. Therm. Anal. Calorim., 90 173–81 (2007).
[6] M. Roy, P. Dave, S.K. Barbar, S. Jangid, D.M. Phase, AM. Awasth, “X-ray, SEM, and DSC studies of ferroelectric Pb1-xBaxTiO3 ceramics”, J. Therm. Anal. Calorim., 101 833–40 (2010).
[7] A. Caneiro, L. Mogni, N. Grunbaum, F. Prado, “Physicochemical properties of non-stoichiometric oxides mixed conductors: part I”, J. Therm. Anal. Calorim., 103 597–606 (2011).
[8] M.L. Moreira, M.F.C. Gurgel, G.P. Mambrini, E.R. Leite, P.S. Pizani, J.A. Varela, E. Longo “Photoluminescence of barium titanate and barium zirconate in multilayer disordered thin films at room temperature”, J. Phys. Chem. A, 112 8938-8942 (2008).
[9] K.M. Lina, C.C. Lina, C.Y. Hsiaob, Y.Y. Lia, “Synthesis of Gd2Ti2O7:Eu3+, V4+ phosphors by sol–gel process and its luminescent properties”, J. Lumin, 127 561-567 (2007).
[10] G.F.G. Freitas, R.S. Nasar, M. Cerqueira, D.M.A. Melo, E. Longo, J.A. Varel, “Luminescence in semi-crystalline zirconium titanate doped with lanthanum”, Mater. Sci. Eng. A., 434 19-22 (2006).
[11] I. Wuled Lenggoro, C. Panatarani, K. Okuyama, “One-step synthesis and photoluminescence of doped strontium titanate particles with controlled morphology”, Mater. Sci.Eng. B. 113 60-66 (2004).
[12] J.K. Park, H. Ryu, H.D. Park, S.Y. Choi, “Synthesis of SrTiO3:Al, Pr phosphors from a complex precursor polymer and their luminescent properties”, J Eur Ceram Soc., 21 535-543 (2001).
[13] L. Hu, H. Song, G. Pan, B. Yan, R. Qin, Q.Dai, “Enhancement of red spectral emission intensity of Y3Al5O12:Ce3+ phosphor via Pr co-doping and Tb substitution for the application to white LEDs”, J. Lumin. 127 371-376 (2007).
[14] A. Sinha, S.R. Nair, P.K. Sinha, “Single step synthesis of Li2TiO3 powder”, J. Nucl. Mater. 399 162-167 (2010).
[15] A.T. De Figueiredo, V.M. Longo, S. De Lazaro, V.R. Mastelaro, F.S. De Vicente, A.C. Hernandes, M. Li Siu, J.A. Varela, E. Longo, Blue-green and red photoluminescence in CaTiO3:Sm, Journal of Luminescence. 126, 403–407, (2007).
[16] Katsumata, T., Kohno, Y., Kubo, H., Komuro S., Morikawa T., ”Low temperature fluorescence thermometer application of long afterglow phosphorescent SrAl12O19: Eu2+,Dy3+ crystals”, Revıew Of Scientific Instruments, 76, 8, (2005).

Year 2015, Volume: 2 Issue: 2, 31 - 47, 20.06.2015

N. Kayacı Serkan Dayan , A. K. Küçük Nilgün Kalaycıoğlu Özpozan , E. Öztürk E. Karacaoğlu

https://doi.org/10.1501/nuclear_0000000011

Abstract

References

[1] W.J. Jaffe, R. Cook, H. Jaffe, “Piezoelectric ceramics”, Academic Press, New York (1971).
[2] M.E. Lines, A.M. Glass, “Principles and applications of ferroelectrics and related materials”, Oxford University Press, Oxford (2001).
[3] J.F. Scott, “Applications of modern ferroelectrics”, Science, 315 954–63 (2007).
[4] Y. Yang, X.H. Wang, C.K. Sun, L.T. Li, “Photoluminescence of high aspect-ratio PbTiO3 nanotube arrays”, J. Am. Ceram. Soc., 91 3820–2 (2008).
[5] G. Nenartaviciene, K. Tonsuaadu, D. Jasaitis, A. Beganskiene, A.Kareiva, “Preparation and characterization of superconducting YBa2(Cu1-xCrx)4O8 oxides by thermal analysis”, J. Therm. Anal. Calorim., 90 173–81 (2007).
[6] M. Roy, P. Dave, S.K. Barbar, S. Jangid, D.M. Phase, AM. Awasth, “X-ray, SEM, and DSC studies of ferroelectric Pb1-xBaxTiO3 ceramics”, J. Therm. Anal. Calorim., 101 833–40 (2010).
[7] A. Caneiro, L. Mogni, N. Grunbaum, F. Prado, “Physicochemical properties of non-stoichiometric oxides mixed conductors: part I”, J. Therm. Anal. Calorim., 103 597–606 (2011).
[8] M.L. Moreira, M.F.C. Gurgel, G.P. Mambrini, E.R. Leite, P.S. Pizani, J.A. Varela, E. Longo “Photoluminescence of barium titanate and barium zirconate in multilayer disordered thin films at room temperature”, J. Phys. Chem. A, 112 8938-8942 (2008).
[9] K.M. Lina, C.C. Lina, C.Y. Hsiaob, Y.Y. Lia, “Synthesis of Gd2Ti2O7:Eu3+, V4+ phosphors by sol–gel process and its luminescent properties”, J. Lumin, 127 561-567 (2007).
[10] G.F.G. Freitas, R.S. Nasar, M. Cerqueira, D.M.A. Melo, E. Longo, J.A. Varel, “Luminescence in semi-crystalline zirconium titanate doped with lanthanum”, Mater. Sci. Eng. A., 434 19-22 (2006).
[11] I. Wuled Lenggoro, C. Panatarani, K. Okuyama, “One-step synthesis and photoluminescence of doped strontium titanate particles with controlled morphology”, Mater. Sci.Eng. B. 113 60-66 (2004).
[12] J.K. Park, H. Ryu, H.D. Park, S.Y. Choi, “Synthesis of SrTiO3:Al, Pr phosphors from a complex precursor polymer and their luminescent properties”, J Eur Ceram Soc., 21 535-543 (2001).
[13] L. Hu, H. Song, G. Pan, B. Yan, R. Qin, Q.Dai, “Enhancement of red spectral emission intensity of Y3Al5O12:Ce3+ phosphor via Pr co-doping and Tb substitution for the application to white LEDs”, J. Lumin. 127 371-376 (2007).
[14] A. Sinha, S.R. Nair, P.K. Sinha, “Single step synthesis of Li2TiO3 powder”, J. Nucl. Mater. 399 162-167 (2010).
[15] A.T. De Figueiredo, V.M. Longo, S. De Lazaro, V.R. Mastelaro, F.S. De Vicente, A.C. Hernandes, M. Li Siu, J.A. Varela, E. Longo, Blue-green and red photoluminescence in CaTiO3:Sm, Journal of Luminescence. 126, 403–407, (2007).
[16] Katsumata, T., Kohno, Y., Kubo, H., Komuro S., Morikawa T., ”Low temperature fluorescence thermometer application of long afterglow phosphorescent SrAl12O19: Eu2+,Dy3+ crystals”, Revıew Of Scientific Instruments, 76, 8, (2005).

There are 16 citations in total.

Details

Primary Language	English
Subjects	Engineering
Journal Section	Articles
Authors	N. Kayacı Serkan Dayan A. K. Küçük Nilgün Kalaycıoğlu Özpozan E. Öztürk E. Karacaoğlu
Publication Date	June 20, 2015
Submission Date	November 13, 2014
Published in Issue	Year 2015Volume: 2 Issue: 2

Cite

APA	Kayacı, N., Dayan, S., Küçük, A. K., Kalaycıoğlu Özpozan, N., et al. (2015). Synthesis and characterization of new phosphor based MTiO3. Journal of Nuclear Sciences, 2(2), 31-47. https://doi.org/10.1501/nuclear_0000000011
AMA	Kayacı N, Dayan S, Küçük AK, Kalaycıoğlu Özpozan N, Öztürk E, Karacaoğlu E. Synthesis and characterization of new phosphor based MTiO3. Journal of Nuclear Sciences. June 2015;2(2):31-47. doi:10.1501/nuclear_0000000011
Chicago	Kayacı, N., Serkan Dayan, A. K. Küçük, Nilgün Kalaycıoğlu Özpozan, E. Öztürk, and E. Karacaoğlu. “Synthesis and Characterization of New Phosphor Based MTiO3”. Journal of Nuclear Sciences 2, no. 2 (June 2015): 31-47. https://doi.org/10.1501/nuclear_0000000011.
EndNote	Kayacı N, Dayan S, Küçük AK, Kalaycıoğlu Özpozan N, Öztürk E, Karacaoğlu E (June 1, 2015) Synthesis and characterization of new phosphor based MTiO3. Journal of Nuclear Sciences 2 2 31–47.
IEEE	N. Kayacı, S. Dayan, A. K. Küçük, N. Kalaycıoğlu Özpozan, E. Öztürk, and E. Karacaoğlu, “Synthesis and characterization of new phosphor based MTiO3”, Journal of Nuclear Sciences, vol. 2, no. 2, pp. 31–47, 2015, doi: 10.1501/nuclear_0000000011.
ISNAD	Kayacı, N. et al. “Synthesis and Characterization of New Phosphor Based MTiO3”. Journal of Nuclear Sciences 2/2 (June 2015), 31-47. https://doi.org/10.1501/nuclear_0000000011.
JAMA	Kayacı N, Dayan S, Küçük AK, Kalaycıoğlu Özpozan N, Öztürk E, Karacaoğlu E. Synthesis and characterization of new phosphor based MTiO3. Journal of Nuclear Sciences. 2015;2:31–47.
MLA	Kayacı, N. et al. “Synthesis and Characterization of New Phosphor Based MTiO3”. Journal of Nuclear Sciences, vol. 2, no. 2, 2015, pp. 31-47, doi:10.1501/nuclear_0000000011.
Vancouver	Kayacı N, Dayan S, Küçük AK, Kalaycıoğlu Özpozan N, Öztürk E, Karacaoğlu E. Synthesis and characterization of new phosphor based MTiO3. Journal of Nuclear Sciences. 2015;2(2):31-47.