Research Article
Ag-Au bimetalik alaşımlı ince filmlerin mikro-X ışını flüoresans sistemi ile homojenliğinin belirlenmesi
Abstract
Bu araştırmanın amacı, farklı Ag-Au oranlarının Ag-Au bimetal alaşımlarının homojenliği üzerindeki etkisini araştırmaktır. Gümüş (Ag) -altın (Au) bimetal alaşımlı ince filmler, Vaksis Termal Evaporatör sistemi ve farklı altın (Au) katkı oranlarında kuvars kristal mikro terazi dedektörü kullanılarak üretildi. Microbeam X-Ray flüoresans spektrometre sistemi, bimetalik Au-Ag alaşımlı ince filmlerin homojenliğini hesaplamak ve farklı konsantrasyon değerleri ile üretim Au-Ag oranlarını hesaplamak için kullanıldı. Hesaplanan oranlar ile üretim değerinin uyumlu olduğu görülmektedir.
Keywords
Project Number
2016/5-47YLS
References
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Determination of the homogeneity of the Ag-Au bimetallic alloy thin films by means of a micro beam X-Ray fluorescence setup with using elemental composition
Abstract
The goal of this work is to research the effect of different Au-Ag ratios on the homogeneity of Au-Ag bimetal alloys. Thin films of silver (Ag)-gold (Au) bimetal alloy were produced using Vaksis Thermal Evaporator system and quartz crystal microbalance detector at different gold (Au) additive ratios. Micro beam X-Ray fluorescence spectrometer system was used to calculate the homogeneity of bimetallic Ag-Au alloy thin films and to calculate production Au-Ag ratios with different concentration values. It is seen that the calculated ratios and production value are in good agreement.
Keywords
Supporting Institution
The author acknowledge the support by 2016/5-47YLS project made in Kahramanmaras Sutcu Imam University USKIM (Kahramamaras TURKEY) and AGH University of Science and Technology (Krakow POLAND).
Project Number
2016/5-47YLS
Thanks
The author also thanks to Prof. Dr. Omer SOGUT, Prof. Dr. Marek LANKOSZ and Dr. Pawel WROBEL for their support.
References
- del Hoyo-Meléndez, J.M., Świt, P., Matosz, M., Woźniak, M., Klisińska-Kopacz, A. and Bratasz, Ł. (2015). Micro-XRF analysis of silver coins from medieval Poland. Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms 349, 6-16. https://doi.org/10.1016/j.nimb.2015.02.018
- Hlozek, M. and Trojek, T. (2017). Silver and tin plating as medieval techniques of producing counterfeit coins and their identification by means of micro-XRF. Radiation Physics Chemistry 137, 234-237. https://doi.org/10.1016/j.radphyschem.2016.08.013
- Ispasoiu, R.G., Balogh, L., Varnavski, O.P., Tomalia, D.A. and Goodson III, T. (2000). Large optical limiting from novel metal− dendrimer nanocomposite materials. Journal of the American Chemical Society 122, 11005-11006. https://doi.org/10.1021/ja0015646
- Jana, N.R. and Peng, X. (2003). Single-phase and gram-scale routes toward nearly monodisperse Au and other noble metal nanocrystals. Journal of the American Chemical Society 125, 14280-14281. https://doi.org/10.1021/ja038219b
- Kanngiesser, B., Malzer, W., Rodriguez, A.F. and Reiche, I. (2005). Three-dimensional micro-XRF investigations of paint layers with a tabletop setup. Spectrochimica Acta Part B: Atomic Spectroscopy 60, 41-47. https://doi.org/10.1016/j.sab.2004.10.012
- Katsifas, C., Touloumzidou, A. and Zachariadis, G. (2019). Compositional study of bronze vessels from the Derveni tombs of central Macedonia of the fourth century bce using energy‐dispersive micro‐X‐ray fluorescence (EDμXRF) spectrometry. Archaeometry 61, 1313-1332. https://doi.org/10.1111/arcm.12486
- Lin, X.Y., Wang, Z.H., Sun, T.X., Pan, Q.L. and Ding, X.L. (2008). Characterization and applications of a new tabletop confocal micro X-ray fluorescence setup. Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms 266, 2638-2642. https://doi.org/10.1016/j.nimb.2007.12.064
- Mantouvalou, I., Lange, K., Wolff, T., Grotzsch, D., Luhl, L., Haschke, M., Hahn, O. and Kanngiesser, B. (2010). A compact 3D micro X-ray fluorescence spectrometer with X-ray tube excitation for archaeometric applications. Journal of Analytical Atomic Spectrometry 25, 554-561.
- Mulvaney, P., Giersig, M. and Henglein, A. (1993). Electrochemistry of multilayer colloids: preparation and absorption spectrum of gold-coated silver particles. The Journal of Physical Chemistry 97, 7061-7064. https://doi.org/10.1021/j100129a022
- Nakano, K. and Tsuji, K. (2010). Development of laboratory confocal 3D-XRF spectrometer and nondestructive depth profiling. Journal of Analytical Atomic Spectrometry 25, 562-569. https://doi.org/10.1039/B916974A
- Sun, Y. and Xia, Y. (2002). Shape-controlled synthesis of gold and silver nanoparticles. Science 298, 2176-2179. https://doi.org/10.1126/science.1077229
- Tsuji, K. and Nakano, K., (2007). Development of confocal 3D micro-XRF spectrometer with dual Cr-Mo excitation. X-Ray Spectrometry 36, 145-149. https://doi.org/10.1002/xrs.957
- Vasilescu, A., Constantinescu, B., Stan, D., Talmatchi, G. and Ceccato, D., (2017). XRF and micro-PIXE studies of inhomogeneity of ancient bronze and silver alloys. Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms 406, 302-308. https://doi.org/10.1016/j.nimb.2017.02.019
- Voegelin, A., Weber, F.-A. and Kretzschmar, R., (2007). Distribution and speciation of arsenic around roots in a contaminated riparian floodplain soil: Micro-XRF element mapping and EXAFS spectroscopy. Geochimica et Cosmochimica Acta 71, 5804-5820. https://doi.org/10.1016/j.gca.2007.05.030
- Wang, R., Yang, J., Zheng, Z., Carducci, M.D., Jiao, J. and Seraphin, S., (2001). Dendron‐controlled nucleation and growth of gold nanoparticles. Angewandte Chemie International Edition 40, 549-552. https://doi.org/10.1002/1521-3773(20010202)40:3<549::AID-ANIE549>3.0.CO;2-P
- Wrobel, P., Czyzycki, M., Furman, L., Kolasinski, K., Lankosz, M., Mrenca, A., Samek, L. and Wegrzynek, D., (2012). LabVIEW control software for scanning micro-beam X-ray fluorescence spectrometer. Talanta 93, 186-192. https://doi.org/10.1016/j.talanta.2012.02.010
There are 16 citations in total.
Details
| Primary Language | English |
|---|---|
| Journal Section | Articles |
| Authors | |
| Project Number | 2016/5-47YLS |
| Publication Date | July 15, 2021 |
| Submission Date | February 9, 2021 |
| Acceptance Date | May 24, 2021 |
| Published in Issue | Year 2021 Volume: 11 Issue: 3 |
